Lapis Lazuli in an Enigmatic ‘Purple7rsquo; Pigment from a Thirteenth-Century BC Greek Wall Painting

Abstract

AbstractAbstractThis paper presents the first evidence of lapis lazuli or lazurite that was detected unexpectedly using micro-Raman spectroscopy during research to identify an enigmatic purple hue on the thirteenth-century BC Greek Bronze Age wall paintings from Gla. The lapis lazuli material was found as part of a mixture including a red iron oxide and an as yet unidentified purple staining material. Existing purple mixtures of that period are also discussed. The identification of lapis lazuli at Gla may prove to be the earliest known use of this pigment in buon fresco, in both Eastern and Western painting traditions. Furthermore, this precedes the next known use of the material as a pigment by 1800 years. The existence of this blue pigment is also discussed within the context of the blue pigment palette of the Bronze Age Aegean and eastern Mediterranean Bronze Age (3300–1100 BC), to show its use in relation to other blue materials and to demonstrate the technology and knowledge mastered by the artists who used this lazurite.