Concepedia

Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters

Nora S. Radu, Frederick J. Hollander, T. Don Tilley, Arnold L. Rheingold

Chemical Communications · 1996 · 63 citations · 21 references

DOI

Concepts

Abstract

The samarium complex Cp*2SmCH(SiMe3)2(Cp*= C5Me5), unlike the related alkyls Cp*2LnCH(SiMe3)3(Ln = Y, Nd), mediates the redistribution of hydrosilanes while being converted to trisamarium clusters, including Cp*6Sm3(µ-SiH3)(µ3-η1,η1,η2-SiH2-SiH2).

References

21

Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes

Gerald Jeske, Harald Lauke, Heiko Mauermann et al. · Journal of the American Chemical Society · 1985 · 533 citations

, , +7

The coordination polymerization of silanes to polysilanes by a ".sigma.-bond metathesis" mechanism. Implications for linear chain growth

T. Don Tilley · Accounts of Chemical Research · 1993 · 435 citations

, , +12

Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series

L. J. Nugent, R.D. Baybarz, J. Burnett et al. · The Journal of Physical Chemistry · 1973 · 314 citations

, , +15

Regioselection and Enantioselection in Organolanthanide-Catalyzed Olefin Hydrosilylation. A Kinetic and Mechanistic Study

Peng-Fei Fu, Laurent Brard, Yanwu Li et al. · Journal of the American Chemical Society · 1995 · 294 citations

, , +7

Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

William J. Evans, Laura Hughes, Timothy P. Hanusa · Journal of the American Chemical Society · 1984 · 222 citations

, , +11