Concepedia

Generation of Organic Cations from Group 14 Organometallic Compounds via Photoinduced Electron Transfer in the Presence of Cu(II) Salt

Kazuhiko Mizuno, Masahiro Yasueda, Yoshio Otsuji

Chemistry Letters · 1988 · 28 citations · 5 references

DOI

Concepts

Abstract

Abstract Irradiations of acetonitrile-alcohol (3 : 1) solutions of arylmethyl silanes, germane, or stannanes in the presence of Cu(BF4)2 gave alkyl arylmethyl ethers in good yields via arylmethyl cations. The efficiency of this photoreaction increased in the order of Si- < Ge- < Sn-compounds.

References

5

Electron-transfer initiated photoaddition of allylsilanes to 1-methyl-2-phenylpyrrolinium perchlorate. A novel allylation methodology

Kazuya Ohga, Patrick S. Mariano · Journal of the American Chemical Society · 1982 · 85 citations

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Exploratory and mechanistic studies of the electron-transfer-initiated photoaddition reactions of allylsilane-iminium salt systems

Kazuya Ohga, Ung Chan Yoon, Patrick S. Mariano · The Journal of Organic Chemistry · 1984 · 84 citations

, , +5

Allylstannane photoadditions to iminium salts. Efficiencies of sequential electron transfer destannation versus desilylation pathways

Robert M. Borg, Patrick S. Mariano · Tetrahedron Letters · 1986 · 29 citations

, , +2

Photochemical Electron-transfer Reaction between Aromatic Olefins and Metal Ions. Dependence of the Reaction Course on the Structure of the Olefins

Masanobu Kojima, Hirochika Sakuragi, Katsumi Tokumaru · Bulletin of the Chemical Society of Japan · 1985 · 23 citations · Full text

, , +13

Photooxidation with Cupric Ions. A Novel Dimethoxylation and Diacetoxylation of Styrene

Shinji Murai, Shigeru Tsutsumi · Bulletin of the Chemical Society of Japan · 1966 · 12 citations

, , +10