Physical Review Letters · 1981 · 66 citations · 11 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsPhysical ChemistrySurface ScienceHigh-pressure ThermodynamicsHydrogen AtomPressure MeasurementSurface AdsorptionSurface PhysicsAdsorption EnergiesAdsorption PropertiesGas Pressure EffectsGaseous StateRecombination ReactionsSurface Recombination
Pressure decay measurements are used to study adsorption and recombination of atomic hydrogen on liquid helium surfaces below 1 K. Recombination is suppressed by five orders of magnitude by applying a 10-T magnetic field. The surface-recombination-rate constant (${K}_{s}$) and the adsorption energy (${\ensuremath{\epsilon}}_{a}$) of H\ensuremath{\downarrow} on $^{4}\mathrm{He}$ are $\frac{{K}_{s}{B}^{2}}{{T}^{\frac{1}{2}}}=(2.6\ifmmode\pm\else\textpm\fi{}0.8)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}7}$ ${\mathrm{cm}}^{2}$ ${\mathrm{T}}^{2}$ ${\mathrm{K}}^{\ensuremath{-}1/2}$ ${\mathrm{sec}}^{\ensuremath{-}1}$ and $\frac{{\ensuremath{\epsilon}}_{a}}{{k}_{\mathrm{B}}}=0.89\ifmmode\pm\else\textpm\fi{}0.07$ K. An estimate of $\frac{{\ensuremath{\epsilon}}_{a}}{{k}_{\mathrm{B}}}=0.59$ K is obtained for H\ensuremath{\downarrow} on a dilute $^{3}\mathrm{He}$-$^{4}\mathrm{He}$ mixture.
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Possible "New" Quantum Systems
Willian C. Stwalley, L. H. Nosanow · Physical Review Letters · 1976 · 170 citations