Physical Review E · 2005 · 32 citations · 23 references
Natural SciencesBiophysicsMolecular PhysicsPolymer ChemistryRheologyPolymer Chain ConformationPolymer ConformationPolymer PhysicsPolymer RheologyPolymer StructurePolymer ThermodynamicsElasticityForce-extension CurvesPartition FunctionPolymer Elasticity ModelsPolymer Statistical MechanicsSemiflexible Polymer PhysicsSemiflexible Polymer TheoryStrong-field Regime
We study theoretically the entropic elasticity of a semiflexible polymer, such as DNA, confined to two dimensions. Using the worm-like-chain model we obtain an exact analytical expression for the partition function of the polymer pulled at one end with a constant force. The force-extension relation for the polymer is computed in the long chain limit in terms of Mathieu characteristic functions. We also present applications to the interaction between a semiflexible polymer and a nematic field, and derive the nematic order parameter and average extension of the polymer in a strong field.
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Quantum Mechanics and Path Integrals
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