Concepedia

New fluorination of organic compounds using thermodynamically unstable nickel fluorides

Neil Bartlett, Richard D. Chambers, Alex J. Roche, Robert C. H. Spink, L. Chacón, J. Marc Whalen

Chemical Communications · 1996 · 32 citations · 4 references

DOI

Concepts

Abstract

Replacement of hydrogen by fluorine in a variety of organic compounds is accomplished with high efficiency in liquid hydrogen fluoride (aHF), at or below 20 °C, using the thermodynamically unstable fluorides RNiF3 and NiF4 the latter prepared in situ from K2NiF6 with BF3.

References

4

Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties

Boris Žemva, Karel Lutar, L. Chacón et al. · Journal of the American Chemical Society · 1995 · 79 citations

, , +7

Free radical chemistry. Part 5. [1] A new approach to the synthesis of perfluorinated ethers

Richard D. Chambers, Brian Grievson, F. G. Drakesmith et al. · Journal of Fluorine Chemistry · 1985 · 43 citations

, , +11

Fluoro(nitrile)xenon(<scp>II</scp>) cations, RCN–XeF<sup>+</sup>AsF<sub>6</sub>–(R = H, CH<sub>3</sub>, CH<sub>2</sub>F, C<sub>2</sub>H<sub>5</sub>, C<sub>2</sub>F<sub>5</sub>, C<sub>3</sub>F<sub>7</sub>, or C<sub>6</sub>F<sub>5</sub>); novel examples of xenon–nitrogen bonds and<sup>129</sup>Xe–<sup>13</sup>C,<sup>129</sup>Xe–<sup>1</sup>H, and<sup>129</sup>Xe-<sup>14</sup>N nuclear spin-spin couplings

Adel A.A. Emara, Gary J. Schrobilgen · Journal of the Chemical Society Chemical Communications · 1987 · 36 citations

, , +11

Free-radical chemistry. Part 8[1]. Electrochemical fluorination of partly fluorinated ethers

Richard D. Chambers, Robert W. Fuss, Michael Jones et al. · Journal of Fluorine Chemistry · 1990 · 25 citations

, , +12