Advanced Synthesis & Catalysis · 2012 · 41 citations · 43 references
Natural SciencesChemistryCatalysisInorganic ChemistryOrganic ChemistryCatalytic MaterialsHeterocyclic ChemistryAsymmetric ReductionsEnantioselective CatalysisEnantioselective SynthesisKetone FunctionalizationKetonesOrganoiridium ChemistryProchiral Ketone Reduction
Abstract An enantioselective hydrosilylation of prochiral ketones was achieved by using a catalytic amount of the readily accessible and air‐ and moisture‐stable iridium complex [IrCl(cod)(NHC)] at room temperature.
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