Advanced Materials · 2013 · 179 citations · 20 references
Optical MaterialsEngineeringStable Blue PhaseMolecule-based MaterialMetamaterialsOrdered BpOptically TunableChemistryElectromagnetic MetamaterialsBp IiOptical PropertiesOptical SystemsNanophotonicsMaterials SciencePhotonicsNon-linear OpticOptoelectronic MaterialsOptical PhysicApplied PhysicsMolecular SwitchBlue Reflections EnabledThin FilmsDynamic Metamaterials
A new light-driven chiral molecular switch doped in a stable blue phase (BP) liquid crystal allows wide optical tunability of three-dimensional cubic nanostructures with a selective reflection wavelength that is reversibly tuned through the visible region. Moreover, unprecedented reversible light-directed red, green, and blue reflections of the self-organized three-dimensional cubic nanostructure in a single film are demonstrated for the first time. Additionally, unusual isothermal photo-stimulated less ordered BP II to more ordered BP I phase transition was observed in the system.
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