Concepedia

ALUMINIUM HALIDE-THIOL SYSTEM: A USEFUL REAGENT FOR DEMETHYLATION OF ALIPHATIC AND AROMATIC METHYL ETHERS AND DEMETHYLENATION OF METHYLENEDIOXY COMPOUNDS

Manabu Node, Kiyoharu Nishide, Midori Sai, Kohei Ichikawa, Kaoru Fuji, Eiichi Fujita

Chemistry Letters · 1979 · 41 citations · 3 references

DOI

Concepts

Abstract

Abstract A new efficient procedure for demethylation of methyl ethers and demethylenation of methylenedioxy compounds under mild conditions has been exploited by the use of aluminium halide-thiol system.

References

3

Demethylation of aliphatic methyl ethers with a thiol and boron trifluoride

Manabu Node, Hitoshi Hori, Eiichi Fujita · Journal of the Chemical Society Perkin Transactions 1 · 1976 · 47 citations

, , +3

Lithium thiomethoxide: A convenient mercaptide reagent

T. Ross Kelly, Hemalata Dali, Wen-Ghih Tsang · Tetrahedron Letters · 1977 · 36 citations

, , +4

Terpenoids. Part 39. Total synthesis of gibberellins A15 and A37

Eiichi Fujita, Manabu Node, Hitoshi Hori · Journal of the Chemical Society Perkin Transactions 1 · 1977 · 13 citations

, , +9