Concepedia

Li<sub>6</sub>PS<sub>5</sub>X: A Class of Crystalline Li‐Rich Solids With an Unusually High Li<sup>+</sup> Mobility

Hans‐Jörg Deiseroth, Shiao‐Tong Kong, Hellmut Eckert, Julia Vannahme, Christof Reiner, Torsten Zaiß, Marc Schlösser

Angewandte Chemie International Edition · 2007 · 961 citations · 21 references

DOI

Concepts

Abstract

Mobile metal ions: Halide-substituted lithium argyrodites form a new class of Li-rich solids with an unusually high Li mobility. Single-crystal X-ray studies (see picture; Li black, S yellow, I red) at room temperature and MAS-NMR measurements in a wide temperature range provide insights into the Li+ ion dynamics.

References

21

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New Lithium-Ion Conducting Crystal Obtained by Crystallization of the Li[sub 2]S–P[sub 2]S[sub 5] Glasses

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