Dalton Transactions · 2012 · 51 citations · 34 references
Natural SciencesChemistryOrganic ChemistryPhysical ChemistryCarbonyl ChemistryCatalytic MechanismsHeterocyclic ChemistryOrganic SynthesisReaction MechanismsAromatic Carbonyl ChemistryC-h Bond ActivationHeterocyclic Reactivity
Aromatic carbonyl compounds in combination with B(C(6)F(5))(3) are able to activate H(2) heterolytically. The reactivity of the carbonyl-B(C(6)F(5))(3) adduct is initiated by its thermal dissociation into components. After H(2) addition, aromatic carbonyl compounds convert into aryl-substituted methanes or alcohols.
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Natural Sciences, Materials Engineering, Materials Science +14
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