Concepedia

o-Vanillyl alcohol as a synthetic equivalent of 2-methoxycyclohexa-2,4-dienones: a novel synthesis of linearly fused cis: anti: cis tricyclopentanoids

Vishwakarma Singh, Beena Thomas

Journal of the Chemical Society Chemical Communications · 1992 · 27 citations · 13 references

DOI

Concepts

Abstract

A novel and efficient synthesis of tricyclopentanoids via inverse demand π4s+π2s cycloaddition and photochemical reaction of annulated[2.2.2]octenones having an α-alkoxy-β,γ-unsaturated carbonyl chromophore, is described.

References

13

A general approach to linearly fused triquinane natural products. Total syntheses of (.+-.)-hirsutene, (.+-.)-coriolin, and (.+-.)-capnellene

Goverdhan Mehta, Akula Narayana Murthy, D. Sivakumar Reddy et al. · Journal of the American Chemical Society · 1986 · 120 citations

, , +8

Intramolecular 1,3-diyl trapping reactions. Total synthesis of (.+-.)-hypnophilin and (.+-.)-coriolin. Formation of the trans-fused bicyclo[3.3.0]octane ring system

Luc Van Hijfte, R. Daniel Little, Jeffrey L. Petersen et al. · The Journal of Organic Chemistry · 1987 · 86 citations

, , +13

Periodate Oxidation of Phenols. IX. Oxidation of o-(omega-Hydroxyalkyl)phenols.

Erich Adler, Synnöve Brasen, Hideo Miyake et al. · Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1971 · 84 citations · Full text

, , +9

Radical translocation reactions of o-iodoanilides: the use of carbon-hydrogen bonds as precursors of radicals adjacent to carbonyl groups

Dennis P. Curran, Ann C. Abraham, Hongtao Liu · The Journal of Organic Chemistry · 1991 · 83 citations

, , +8

The structure and chemistry of hirsutic acid

F. Comer, Frank McCapra, I. H. Qureshi et al. · Tetrahedron · 1967 · 81 citations

, , +3