Journal of the Chemical Society A Inorganic Physical Theoretical · 1969 · 22 citations · 0 references
Inorganic Chemistry1,4-Thioxan ComplexesEngineeringType Rex4l2Group Vib AtomsNatural SciencesCoordination ComplexSulphur-to-rhenium BondingOrganic ChemistryMolecular ComplexQuantum ChemistryChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
Complexes of the type ReX4L2 and ReOX3L2(X = Cl or Br; L = tetrahydrofuran, 1,4-dioxan, 1,4-thioxan and 1,4-dithian) have been prepared. Far-i.r. and H n.m.r. measurements were used to assign the stereochemistry, and in the case of the 1,4-thioxan complexes, sulphur-to-rhenium bonding has been established.