Green Chemistry · 2010 · 139 citations · 60 references
Polymer-incarcerated Gold NanoclustersChemical EngineeringCatalytic ApplicationEngineeringIndustrial CatalysisAmbient ConditionsMetal NanoparticlesGreen ChemistryCatalyst RecyclingNanoheterogeneous CatalysisCatalysisChemistryBenign Aerobic OxidationAerobic Oxidative EsterificationSimple OperationsPolymer ChemistryCatalytic Synthesis
Environmentally benign aerobic oxidation of alcohols to methyl esters catalyzed by polymer-incarcerated gold nanoclusters (PI-Au) was developed and reactions proceeded under very mild conditions. The catalyst could be recovered by simple operations without significant loss of activity.
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A. Stephen K. Hashmi, Graham J. Hutchings · Angewandte Chemie International Edition · 2006 · 3.4K citations