Concepedia

Reaction of Arylglyoxals with Electron‐Rich Benzenes and π‐Excessive Heterocycles. Facile Synthesis of Heteroaryl α‐Acyloins

Sergey P. Ivonin, Andrey V. Lapandin, Andrey A. Anishchenko, Vasiliy G. Shtamburg

Synthetic Communications · 2004 · 30 citations · 8 references

DOI

Concepts

Abstract

Abstract The reaction of arylglyoxals and their hydrates with electron‐rich benzenes and π‐excessive heterocycles, if conducted in the absence of catalysts, affords α‐benzoins.

References

8

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.alpha.-Heterosubstituted phosphonate carbanions. 11. Benzoins via an acyl anion equivalent. Novel one-pot preparation of benzo[b]furans via benzoins using hydriodic acid

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Amino group protection in peptide synthesis. 4,5-Diphenyl-4-oxazolin-2-one group

John C. Sheehan, Frank S. Guziec · The Journal of Organic Chemistry · 1973 · 37 citations

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Reductive coupling of benzoyl cyanide and carbonyl compounds by aqueous titanium(III) ions. A new convenient and selective access to the less stable mixed benzoins

Angelo Clerici, Ombretta Porta · The Journal of Organic Chemistry · 1993 · 27 citations

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Application of cyanophosphates in organic synthesis. Reactivity of .ALPHA.-cyano-.ALPHA.-diethylphosphonooxy anions.

Takushi Kurihara, Kazunori Santo, Shinya Harusawa et al. · Chemical and Pharmaceutical Bulletin · 1987 · 24 citations · Full text

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