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Brueckner-Goldstone Many-Body Theory for the Hyperfine Structure of Phosphorus
56
Citations
10
References
1968
Year
Crystal StructureEngineeringHyperfine StructurePhysicsNatural SciencesAtomic PhosphorusApplied PhysicsAtomic PhysicsWeak InteractionPhysical ChemistryComputational ChemistryHfs ConstantChemistryQuantum ChemistryCorrelation ContributionElectronic StructureMany-body Problem
The Brueckner-Goldstone many-body perturbation theory is utilized to study the hyperfine interaction in atomic phosphorus. By this method, a correlation contribution to the hfs constant of a positive sign and an appropriate magnitude is obtained, which predominates over the negative core-polarization effect to produce substantial agreement with experiment.
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