A new graphene-modified protic ionic liquid-based composite membrane for solid polymer electrolytes

TLDR

Producing solid polymer electrolytes that combine high ionic conductivity with robust mechanical strength remains a key fabrication challenge. The study introduces a PIL(NTFSI)-G composite membrane that dramatically improves ionic conductivity and mechanical strength at minimal loading. Graphene sheets form a homogeneous 3‑D network within the polymer matrix, creating continuous ion‑transfer channels and reinforcing nanofiller–matrix adhesion. The PIL(NTFSI)-G composite achieves 257.4 % higher ionic conductivity, 345 % stronger tensile strength, offers a 20 % cost saving by reducing PIL load, and represents a promising route for polymer electrolyte design.

Abstract

The production of a solid polymer electrolyte with high ionic conductivity and mechanical properties is the main fabrication challenge in application of polymer electrolyte membranes. This paper describes a novel polymer electrolyte membrane using protic ionic liquids (PILs) with ionic liquid polymer modified graphene (G) sheets [denoted PIL(NTFSI)-G] that exhibit dramatic enhancements in ionic conductivity (257.4%) and mechanical properties (345% improvement in tensile strength and a near 25-fold increase in modulus were achieved at 150 °C) with a minimal loading of PIL(NTFSI)-G (0.5 wt%). The addition of graphene, by sparing the high-cost PIL addition, gives a 20% cost-saving. The homogeneous distribution of graphene sheets as a 3D network through the polymer matrix in the composite membrane provides a high degree of continuous and interconnected transfer channels to facilitate ion transfer and enhance nanofiller–matrix adhesion to reinforce mechanical properties. This newly developed material provides a potential route toward the design and fabrication of polymer electrolytes.