Concepedia

Migration of Silicon from Oxygen to Carbon in O-Trialkylsilyl Ketene Acetals

Stanley Raucher, Deborah C. Schindele

Synthetic Communications · 1987 · 14 citations · 10 references

DOI

Concepts

Abstract

Abstract The migration of silicon from oxygen to carbon for 1 and 3 is intramolecular. The half—life of migration is not influenced by the presence of t-BuMe2SiCI or triethyIbenzylammonium chloride.

References

10

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Robert E. Ireland, Richard H. Mueller, Alvin K. Willard · Journal of the American Chemical Society · 1976 · 807 citations

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Accounts of Chemical Research · 1974 · 713 citations

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Ketene alkyltrialkylsilyl acetals: synthesis, pyrolysis and NMR studies

C. Ainsworth, Yu-Neng Kuo · Journal of Organometallic Chemistry · 1972 · 225 citations

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O-Silylation and Attempted O-Alkylation of Lithium Ester Enolates. The Synthesis of O-Silyl Ketene Acetals

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