Journal of the American Chemical Society · 2014 · 120 citations · 33 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOrganic ChemistryPolymer ChemistryIon ExchangeIonic PolymersPolymerization ChemistryPolymerization Reaction EngineeringIn Situ PolymerizationIon Exchange MaterialsIon Exchange ReactionsIon-exchange PolymersIon-exchange ResinsMetal-organic Framework CompositesMetal-organic Framework SynthesisMetal-organic Frameworks
A porous metal-organic framework composite with flexible anion-exchange polymers threaded within the host cavity demonstrates very fast and reversible ion-exchange activity. Polyvinyl benzyl trimethylammonium hydroxide (PVBTAH) caged in ZIF-8 is synthesized in steps of chloro-monomer impregnation, in situ polymerization, amination, and alkaline ion exchange. The synthesized non-cross-linked PVBTAH∼ZIF-8 material exhibits superior ion-exchange kinetics compared to conventional ion-exchange resins.
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