Concepedia

Persistent Tris(t-butyldimethylsilyl)silyl Radical and Its New Generation Methods

Mitsuo Kira, Takeshi Obata, Itaru Kon, Hisako Hashimoto, Masaaki Ichinohe, Haruaki Sakurai, Soichiro Kyushin, Hideyuki Matsumoto

Chemistry Letters · 1998 · 42 citations · 13 references

DOI

Concepts

Abstract

Abstract A persistent silyl radical, tris(t-butyldimethylsilyl)silyl radical, (t-BuMe2Si)3Si· (1), was produced by two new methods in addition to a conventional hydrogen abstraction from the corresponding hydrosilane: one-electron oxidation of (t-BuMe2Si)3SiNa (2) by NO+BF4− and one-electron reduction of (t-BuMe2Si)3SiBr (3) by sodium.

References

13

Hexa‐<i>tert</i>‐butyldisilane–the Molecule with the Longest SiSi Bond

Nils Wibeŕg, Harald Schuster, Arndt Simon et al. · Angewandte Chemie International Edition in English · 1986 · 149 citations

, , +5

Electron spin resonance of organosilyl radicals in solution

Paul J. Krusic, Jay K. Kochi · Journal of the American Chemical Society · 1969 · 108 citations

, , +8

Structure of the Methyl Radical and Other Radicals

Linus Pauling · The Journal of Chemical Physics · 1969 · 95 citations

, , +1

Triaryl-silyl, -germyl, and -stannyl radicals .MAr3 (M = Si, Ge, or Sn and Ar = 2,4,6-Me3C6H2) and .Ge(2,6-Me2C6H3)3: Synthesis and ESR studies

M. J. S. GYNANE, Michael F. Läppert, Paul I. Riley et al. · Journal of Organometallic Chemistry · 1980 · 75 citations

, , +2

Subvalent Group 4B metal alkyls and amides. Part 4. An electron spin resonance study of some long-lived photochemically synthesised trisubstituted silyl, germyl, and stannyl radicals

Andrew Hudson, Michael F. Läppert, Peter W. Lednor · Journal of the Chemical Society Dalton Transactions · 1976 · 73 citations

, , +13