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Diazobutanol complexes of molybdenum and tungsten from the reaction of bis[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)molybdenum or -tungsten with tetrahydrofuran in the presence of alkyl bromides
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1977
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Diazobutanol ComplexesInorganic ChemistryChemical EngineeringEngineeringCoordination ComplexAlkyl BromidesOrganometallic CatalysisMolecular ComplexChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
Complexes of the type [M(N2)2(dppe)2][M = Mo or W; dppe = 1,2-bis(diphenylphosphino)ethane] react with tetrahydrofuran in the presence of alkyl bromides to form [MBr(NN–[graphic omitted]H2)(dppe)2] which are converted by H+ into [MBr(N–NCHCH2CH2CH2OH)(dppe)2]+. The mechanism of this reaction is discussed.