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DEPROTECTION OF 1,1-DIACETATES WITH [NO<sup>+</sup>⋅ CROWN ⋅ H(NO<sub>3</sub>)<sub>2</sub><sup>−</sup>]
19
Citations
40
References
2002
Year
Room TemperatureChemical EngineeringIonic ComplexEngineeringNucleic Acid ChemistryBiochemistryNatural SciencesMacrocyclic PolyetherOrganic ChemistryCatalysisChemistryGene ExpressionSynthetic ChemistryInorganic SynthesisInorganic Compound
ABSTRACT An ionic complex has been obtained from N2O4 in the presence of the macrocyclic polyether 18-crown-6. This crystalline compound was used as an effective deprotecting agent for the conversion of 1,1-diacetates to their corresponding aldehydes at room temperature with quantitative yields.
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