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X-Ray structure of the non-classically bonded carbonium ion [{(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)<sub>2</sub>}<sub>2</sub>(C<sub>3</sub>H<sub>5</sub>)]<sup>+</sup>
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1977
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X-ray CrystallographyInorganic ChemistryMaterials ScienceX-ray SpectroscopyFe AtomBiochemistryEngineeringX-ray StructureAllylic SystemNatural SciencesX-ray DiffractionChemical BondCh2 GroupOrganometallic CatalysisMain Group ChemistryChemistryMolecular ChemistryCrystallography
In the cation [{(η5-C5H5)Fe(CO)2}2(C3H5)]+, each Fe atom is joined by a strong β-bond to a CH2 group and by a weak link to the β-CH group of the allylic system.