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Surface Recognition of Dipolar Molecules Entering Channels of the Organic Zeolite Tris(o-phenylenedioxy)cyclotriphosphazene
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2001
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Optical MaterialsEngineeringOrganic ChemistryChemistryOrganic Zeolite TrisSurface RecognitionMolecular RecognitionZeoliteBiophysicsCrystal MaterialPhotonic MaterialsPhysical ChemistryCrystallographyOrganic Material ChemistryOrganic ZeoliteSurface ChemistryMolecular SwitchCrystalsMolecule-based MaterialPolar Crystals
Macroscopically polar crystals of an organic zeolite, tris(o-phenylenedioxy)cyclotriphosphazene, are obtained by partial guest exchange of included THF molecules with nonlinear optical molecules, which enter the channels via a mechanism of surface recognition (4-amino-4′-nitrobiphenyl partially (left) and fully (right) stained crystals are shown in the Figure).