Concepedia

Bis(η<sup>6</sup>‐phosphabenzene)vanadium: Synthesis, Structure, Redox Properties, and Conformational Flexibility

Christoph Elschenbroich, Mathias Nowotny, Bernhard Metz, Werner Massa, J. Graulich, Karl Biehler, Wolfgang Sauer

Angewandte Chemie International Edition in English · 1991 · 77 citations · 11 references

DOI

Concepts

Abstract

Metal–ligand condensation was used to prepare the first binary heteroarene complex of a group 15 metal, bis(η6-phosphabenzene)-vanadium (1). It was fully characterized by EPR spectroscopy, X-ray structure analysis, ligand and to the analogous benzene complex, 1 is thermally stable and is very stable toward oxidizing agents.

References

11

The crystal and molecular structure of 1,1,2,2,9,9,10,10-octafluoro-[2,2]paracyclophane and a reinvestigation of the structure of [2,2]paracyclophane

H. Hope, Joel Bernstein, K. N. Trueblood · Acta Crystallographica Section B · 1972 · 272 citations

, , +9

The Group 5 heterobenzenes

Arthur J. Ashe · Accounts of Chemical Research · 1978 · 190 citations

, , +6

Applications of photoelectron spectroscopy. 41. Photoelectron spectra of phosphabenzene, arsabenzene, and stibabenzene

Christopher Batich, E. Heilbronner, Volker Hornung et al. · Journal of the American Chemical Society · 1973 · 150 citations

, , +5

The Electrochemical Reduction of Benzene—First Direct Determination of the Reduction Potential

John Mortensen, Jürgen Heınze · Angewandte Chemie International Edition in English · 1984 · 107 citations

, , +16

Temporary anion states of phosphabenzene, arsabenzene, and stibabenzene. Trends in the .pi. and .pi.* orbital energies

P. D. Burrow, Arthur J. Ashe, Dennis J. Bellville et al. · Journal of the American Chemical Society · 1982 · 84 citations

, , +10