Concepedia

An Arsinidene as a Cubane‐Type Structural Unit: Synthesis and Structure of [(CO)<sub>3</sub>Fe—AsCH<sub>3</sub>]<sub>4</sub>

Erika Röttinger, Heinrich Vahrenkamp

Angewandte Chemie International Edition in English · 1978 · 17 citations · 6 references

DOI

Concepts

Abstract

The first cubane complex of iron to contain no sulfur has the formula [(CO)3FeAsCH3]4 Its synthesis utilized the thermolability of the AsH bond in complexes: (CO)4Fe.CH3AsH2 decomposes slowly at room temperature, and faster on heating, to form the Fe4As4 Cubane.

References

6

Sulfur Atoms as Ligands in Metal Complexes

Heinrich Vahrenkamp · Angewandte Chemie International Edition in English · 1975 · 206 citations

, , +17

Synthesis, structure, and bonding of a mono(organo)phosphido-bridged tetracobalt carbonyl cluster, di-.mu.2-carbonyl-di-.mu.4-phenylphosphido-octacarbonyltetracobalt. New mode of transition metal coordination for a PR ligand

Robert C. Ryan, Lawrence F. Dahl · Journal of the American Chemical Society · 1975 · 101 citations

, , +16

Organometallic pnicogen complexes. V. Preparation, structure, and bonding of the tetrameric antimony-cobalt cluster system, Co4(CO)12Sb4: the first known (main group element)(metal carbonyl) cubane-type structure

Lawrence F. Dahl, A. S. FOUST · Journal of the American Chemical Society · 1970 · 70 citations

, , +16

C<sub>6</sub>H<sub>5</sub>P[Mn(CO)<sub>2</sub>C<sub>5</sub>H<sub>5</sub>]<sub>2</sub>: A Phosphinidene Complex with Trigonal Planar Coordinated Phosphorus(<scp>I</scp>)

Gottfried Hüttner, Hans‐Dieter Müller, Albin Frank et al. · Angewandte Chemie International Edition in English · 1975 · 67 citations

, , +12

Arsinidene Complexes: Structure and Electronic Spectrum of C<sub>6</sub>H<sub>5</sub>As[Cr(CO)<sub>5</sub>]<sub>2</sub>

Gottfried Hüttner, Joachim von Seyerl, Mario Marsili et al. · Angewandte Chemie International Edition in English · 1975 · 44 citations

, , +14