Titanium enolates and “ate” complexes of N,N-disubstituted amides and thioamides in the Michael reaction.

<b>Hard and Soft Acids and Bases</b>

Ralph G. Pearson · Journal of the American Chemical Society · 1963 · 10.2K citations

Natural Sciences, Biochemistry, Chemistry +5

Enantioselective Michael reactions. Diastereoselective reactions of chlorotitanium enolates of chiral N-acyloxazolidinones with representative electrophilic olefins

David A. Evans, Mark T. Bilodeau, Todd C. Somers et al. · The Journal of Organic Chemistry · 1991 · 148 citations

Natural Sciences, Chemistry, Organic Chemistry +6

Asymmetric aldol reactions. Use of the titanium enolate of a chiral N-acyloxazolidinone to reverse diastereofacial selectivities

Maryellen Nerz-Stormes, Edward R. Thornton · The Journal of Organic Chemistry · 1991 · 145 citations

Natural Sciences, Chemistry, Catalysis +12

Erythro selective aldol condensation using titanium enolates

Manfred T. Reetz, Roland Peter · Tetrahedron Letters · 1981 · 135 citations

Pharmacy, Chemistry, Medicinal Chemistry +7

Acyclic stereoselection. 46. Stereochemistry of the Michael addition of N,N-disubstituted amide and thioamide enolates to .alpha.,.beta.-unsaturated ketones

D. A. OARE, Mark Henderson, Mark A. Sanner et al. · The Journal of Organic Chemistry · 1990 · 127 citations

Natural Sciences, Chemistry, Mass Spectrometric Analysis +6