Concepedia

Carbonylation of methanol in supercritical CO2 catalysed by a supported rhodium complex

R.J. Sowden, Murielle Sellin, Nicola De Blasio, David J. Cole‐Hamilton

Chemical Communications · 1999 · 33 citations · 4 references

DOI

Concepts

Abstract

A rhodium complex supported on polyvinylpyrrolidone catalyses the carbonylation of methanol to methyl ethanoate and ethanoic acid in supercritical CO2 at rates up to ca. 50% those in liquid solution but with minimal catalyst leaching.

References

4

Iridium-Catalyzed Enantioselective Hydrogenation of Imines in Supercritical Carbon Dioxide

Sabine Kainz, Axel Brinkmann, Walter Leitner et al. · Journal of the American Chemical Society · 1999 · 300 citations

, , +12

C1 to acetyls: catalysis and process

Mark J. Howard, Michael D. Jones, M. S. ROBERTS et al. · Catalysis Today · 1993 · 186 citations

, , +7

Activity and Stability of Two Polymer-Supported Rhodium-Based Catalysts for the Vapour Phase Carbonylation of Methanol

Nicola De Blasio, E. Tempesti, A. Kaddouri et al. · Journal of Catalysis · 1998 · 30 citations

, , +13

The relative importance of heterogeneous and homogeneous methanol carbonylation using supported rhodium catalysts in the liquid phase

Nicola De Blasio, Margaret Robson Wright, E. Tempesti et al. · Journal of Organometallic Chemistry · 1998 · 22 citations

, , +13