Concepedia

Reaction of alkenyl-ruthenium(II) Ru(CO)Cl(RC=CHR′(PPh3)2 complexes with CO. Formation of dicarbonyl complexes or η2-acyl complexes depending on the R and R′ groups

Hassane Loumrhari, Josep Ros, M.R. Torres, Amelia Santos, Antonio M. Echavarren

Journal of Organometallic Chemistry · 1991 · 30 citations · 10 references

DOI

Concepts

References

10

Insertion reactions of the 16-electron complexes MHCl(CO)[P(CHMe2)3]2 (M = Ru, Os) with alkynes. The x-ray crystal structure of [(E)-PhCH:CHOs(Cl)(CO)[P(CHMe2)3]2

Helmut Werner, Miguel A. Esteruelas, Heiko Otto · Organometallics · 1986 · 182 citations

Insertion reactions of acetylenes with hydridocarbonyl-chlorotris(triphenylphosphine)ruthenium(II). X-ray structure of carbonylchloro(cis-1,2-diphenylethenyl)bis(triphenylphosphine)ruthenium(II)

M.R. Torres, Aurora Santos, Josep Ros · Journal of Organometallic Chemistry · 1986 · 161 citations

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Five and six CO-ordinate σ-aryl derivatives of Ru(II) and Os(II) and the equilibrium RuRX(CO)2 (PPh3)2⇄ Ru[C(O)R]X(CO) (PPh3)2

W.R. Roper, L.J. Wright · Journal of Organometallic Chemistry · 1977 · 96 citations

, , +3

Insertion reactions of dimethyl acetylenedicarboxylate with alkenylruthenium complexes of the type [Ru(CO)Cl(R′CCHR)(PPh3)2]. The crystal structure of [RCCC(CO2Me)-CHCHCMe3}(PPh3)2]

M.R. Torres, Aurora Santos, Josep Ros · Journal of Organometallic Chemistry · 1987 · 59 citations

.eta.2-Acyl coordination and .beta.-carbon-hydrogen bond interaction in acyl complexes of molybdenum. Crystal and molecular structures of tris(trimethylphosphine)carbonylchloro(.eta.2-trimethylsilylacetyl)molybdenum [Mo(.eta.2-COCH2SiMe3)Cl(CO)(PMe3)3] and the cyclic complex [cyclic] Mo(COCH3)(S2CNMe2)(CO)(PMe3)2

Ernesto Carmona, Luis Sánchez, José M. Marín et al. · Journal of the American Chemical Society · 1984 · 54 citations

, , +10