Concepedia

Three‐coordinate divalent Group 14 element derivatives and related compounds

Isabelle Saur, Sonia Garcia Alonso, Jacques Barrau

Applied Organometallic Chemistry · 2005 · 74 citations · 121 references

DOI

Concepts

Abstract

Abstract This review describes recent work on the synthesis, spectroscopic analysis, structures and investigation of chemical behaviours of new subvalent germanium and tin compounds supported by the β‐diketiminato ligand L 2 (L 2 = NPhC(Me)CHC(Me)NPh), namely the divalent species L 2 (X)M, the germane and stannane chalcogenones L 2 (X)MY, the heavier Group 14 element transition‐metal complexes L 2 (X)MM′(CO) n and the cationic germanium–transition‐metal complexes [L 2 Ge + M′(CO) n ]. Copyright © 2005 John Wiley & Sons, Ltd.

References

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