Concepedia

Synthesis of new chiral phosphines for asymmetric catalysis

Henri B. Kagan, J.‐C. Fiaud, Chloé Hoornaert, Dominique Meyer, J.C. Poulin

Bulletin des Sociétés Chimiques Belges · 1979 · 51 citations · 20 references

DOI

Concepts

Abstract

Abstract A new analog 6a of diop is prepared from D‐mannitol. The synthesis of the 1,3‐diphosphine 9a and of 1,2‐aminomonophosphine 12 are described. All these phosphines behave presumably as bidentate ligands, their efficiency in asymmetric catalysis are compared in a set of reactions involving asymmetric C‐H or C‐C bond formations.

References

20

Methods in Carbohydrate Chemistry

J. S. Brimacombe · Carbohydrate Research · 1994 · 1.2K citations

, , +3

Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine

Henri B. Kagan, Tuan-Phat Dang · Journal of the American Chemical Society · 1972 · 1K citations

, , +12

Asymmetric synthesis. Production of optically active amino acids by catalytic hydrogenation

Michael D. Fryzuk, B. Bosnich · Journal of the American Chemical Society · 1977 · 545 citations

, , +15

Asymmetric hydrogenation with a complex of rhodium and a chiral bisphosphine

William S. Knowles, M. J. Sabacky, B. D. Vineyard et al. · Journal of the American Chemical Society · 1975 · 431 citations

, , +19

Asymmetric catalytic reduction with transition metal complexes. II. Asymmetric catalysis by a supported chiral rhodium complex

Willy Dumont, J.C. Poulin, Dang Tuan Phat et al. · Journal of the American Chemical Society · 1973 · 329 citations

, , +10