Concepedia

An Isolable, Oxygen-Coordinated Silver(I) Complex of Dimethyl Diazomalonate:  Synthesis and Characterization of [HB(3,5-(CF<sub>3</sub>)<sub>2</sub>Pz)<sub>3</sub>]Ag[OC(OCH<sub>3</sub>)]<sub>2</sub>CN<sub>2</sub> (Where Pz = Pyrazolyl)

H. V. Rasika Dias, S.A. Polach

Inorganic Chemistry · 2000 · 32 citations · 16 references

DOI

Concepts

Abstract

The use of a highly fluorinated tris(pyrazolyl)borate ligand to stabilize a silver(I) adduct containing dimethyl diazomalonate is described. [HB(3,5-(CF3)2Pz)3]Ag[OC(OCH3)]2CN2 is a thermally stable solid (ca 90 °C). It shows an uncommon coodination mode for a diazoalkane ligand.

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