Concepedia

Synthesis of aluminium triflate-grafted MCM-41 as a water-tolerant acid catalyst for the ketalization of glycerol with acetone

Kamlesh N. Tayade, Manish Kumar Mishra, K. Munusamy, Rajesh S. Somani

Catalysis Science & Technology · 2015 · 41 citations · 59 references

DOI

Concepts

Abstract

An aluminium triflate species grafted over MCM-41 (Al(TF)–MS) was synthesized by a novel route as an inexpensive and water-tolerant solid acid catalyst for the ketalization of glycerol with acetone to solketal (solketal synthesis).

References

59

Development of Novel Lewis Acid Catalysts for Selective Organic Reactions in Aqueous Media

Shu̅ Kobayashi, Kei Manabe · Accounts of Chemical Research · 2002 · 755 citations

, , +12

Scandium Triflate in Organic Synthesis

Shu̅ Kobayashi · European Journal of Organic Chemistry · 1999 · 435 citations

, , +13

Lewis Acid Catalysts Stable in Water. Correlation between Catalytic Activity in Water and Hydrolysis Constants and Exchange Rate Constants for Substitution of Inner-Sphere Water Ligands

Shu̅ Kobayashi, Satoshi Nagayama, Tsuyoshi Busujima · Journal of the American Chemical Society · 1998 · 368 citations

, , +10

Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetals

J. Deutsch, Andreas Martin, H. Lieske · Journal of Catalysis · 2006 · 305 citations

, , +6

Use of lanthanide(III) ions as catalysts for the reactions of amines with nitriles

John H. Forsberg, Vincent T. Spaziano, T. M. Balasubramanian et al. · The Journal of Organic Chemistry · 1987 · 281 citations

, , +10