Prepreg aging in relation to tack

Abstract

Abstract Thermoanalytical measurements and tack tests were both performed using a commercially available carbon fiber/epoxy prepreg system (Hercules 3501–6) to examine changes caused by aging as they affect handling and processability of thermosetting matrix‐based composites. Combining these techniques, a relationship between prepreg bulk and surface characteristics in relation to aging was investigated. Isothermal kinetic studies at low temperatures showed maximum conversions (α m ) that increased with increasing cure temperatures. In addition, a linear relationship between glass transition temperatures ( T g ) and conversions (α) was observed regardless of aging (or cure) temperatures. Energy of separation of prepreg stacks, which may be viewed as a measure of prepreg tack, showed a maximum value at a specific temperature. The maximum energy of separation was observed in the temperature range of 20–25°C above the glass transition temperature for a given sample. However, the maximum energy of separation values decreased with increasing aging times (or conversions), implying that prepreg tack was a viscoelastic property rather than a viscous property of the resin matrix in the prepreg.