Unusual reaction between a cationic carbyne complex of rhenium and nucleophiles containing a carbonyliron dianion to form a dimetal complex with a bridging carbene ligand. Syntheses and crystal structures of [.eta.-C5H5(CO)2Re(.mu.-CHC6H5)Fe(CO)4], [.eta.-C5H5(CO)2Re:C(OC2H5)C6H5], and [.eta.-C5H5(CO)2BrReCH2C6H5]

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUnusual reaction between a cationic carbyne complex of rhenium and nucleophiles containing a carbonyliron dianion to form a dimetal complex with a bridging carbene ligand. Syntheses and crystal structures of [.eta.-C5H5(CO)2Re(.mu.-CHC6H5)Fe(CO)4], [.eta.-C5H5(CO)2Re:C(OC2H5)C6H5], and [.eta.-C5H5(CO)2BrReCH2C6H5]Jiabi Chen, Yong Yu, Kun Liu, Guang Wu, and Peiju ZhengCite this: Organometallics 1993, 12, 4, 1213–1220Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April 1993https://pubs.acs.org/doi/10.1021/om00028a041https://doi.org/10.1021/om00028a041research-articleACS PublicationsRequest reuse permissionsArticle Views89Altmetric-Citations39LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts