Metal–metal interaction in polynuclear silver(<scp>I</scp>) complexes: spectroscopy, luminescent properties and X-ray crystal structure of [Ag<sub>3</sub>(dppp)<sub>2</sub>(MeCN)<sub>2</sub>(ClO<sub>4</sub>)<sub>2</sub>]<sup>+</sup>[dppp = bis(diphenylphosphinophenylphosphine)]

Chi‐Ming Che, Dan Li, Shie‐Ming Peng, Gene-Hsian Lee, Yaw-Ming Wang, Shiuh‐Tzung Liu

Journal of the Chemical Society Chemical Communications · 1991 · 65 citations · 24 references

Concepts

Abstract

The [Ag3(dppp)2(MeCN)2(ClO 4)2]+ complex displays 1(d σ* → pσ) transition at 288 nm and solid state photoluminescence at 467 nm; the Ag-Ag distances are 2.943-3. 014 (2) Å.

References

24