Sesquiterpenoids from Dittrichia viscosa (L.) GREUTER. Their structure and deterrent activity

W. M. Daniewski, W. Kroszczyński, Ełżbieta Błoszyk, Bohdan Drożdż, J. Nawrot, Urszula Rychłewska, Miloš Buděšı́nský, Miroslav Holub

Collection of Czechoslovak Chemical Communications · 1986 · 13 citations · 0 references

Concepts

Abstract

In addition to the earlier described inuviscolide ( II ), the sesquiterpenic vachanic ( V ) and 2α-hydroxyisocostic ( VII ) acids, as well as carabron ( VIII ) and the so far undescribed sesquiterpenic lactone 11αH,13-dihydroconfertin were also isolated from Dittrichia viscosa (L.) GREUTER. For the last mentioned lactone the structure IX has been derived. The structure of vachanic acid ( V ) was confirmed by X-ray structural analysis. Compounds V to VII were tested for their deterrent (antifeedant) activity against selected insect pests living in corn stores, and they generally had a high activity.