Acta Crystallographica Section E Structure Reports Online · 2009 · 14 citations · 16 references
Natural SciencesChemistryCrystal StructureOrganic ChemistryOrganometallic ChemistryCoordination ChemistryCrystal ChemistryCrystal SystemsCrystallographyMolecular SymmetryStructure DeterminationChainsCrystal Packing GeometryInfinite ChainsOctahedral CoordinationPackingTetrahedral ComplexesTetrahedral Coordination
In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol-ecule in the asymmetric unit. The Hg atom has a distorted tetra-hedral coordination involving the S atoms of two 1-butyl-3-propyl-thio-urea groups and the C atoms of the two CN(-) anions. In the crystal packing, adjacent mol-ecules are connected by inter-molecular N-H⋯N and N-H⋯S hydrogen bonds, forming infinite chains in three dimensions.
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A short history of<i>SHELX</i>
George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text
Mercury(II) complexes of heterocyclic thiones.
Zora Popović, Gordána Pavlović, Dubravka Matković‐Čalogović et al. · Inorganica Chimica Acta · 2000 · 79 citations