Angewandte Chemie International Edition in English · 1994 · 96 citations · 11 references
Natural SciencesChemistryMaterials ScienceChemical KineticsPhysical ChemistryThermodynamicsAddition ReactionsChemical Reaction KineticsChemical ThermodynamicsEntropyPhase EquilibriaStoichiometryMulticomponent Reaction ThermodynamicsNonisothermal Rate LawsTemperature-dependent Kinetics
The same compound, 1,2,3,4-C60H4(1), is both the major kinetic product of the reaction of C60 or C60H2 with BH3 and the thermodynamically most stable isomer of C60H4. This was predicted by ab initio calculations and confirmed by experiment.
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Synthesis of Isomerically Pure Organodihydrofullerenes
Andreas Hirsch, Thomas Grösser, Andreas Skiebe et al. · Chemische Berichte · 1993 · 235 citations