Rhodium Derivatives of Peroxoboronic Acids and Peroxoboric Acid: Formation of Metallatrioxaborolanes from an η²‐Peroxo Complex

Abstract

Heterocyclic peroxides with a five-membered RhOOBO ring have been isolated by reaction of a rhodium peroxo complex with phenylboronic acids. They can be considered to be rhodium derivatives of perboric acid (see scheme) and phenylperboronic acids.