Publication | Closed Access
Chiral Ligands to Support Self-Assembly of [LPdCl]<sub>3</sub> Trimers via a Set of Secondary Interactions
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Citations
29
References
2009
Year
Chiral LigandsSupport Self-assemblySecondary InteractionsEngineeringHeterocyclicCross-coupling ReactionTrimeric PalladacyclesNatural SciencesTrimeric MoleculesMolecular BiologyOrganic ChemistryOrganometallic CatalysisMolecular ComplexChemistryHeterocycle ChemistrySupramolecular ChemistryTrimeric Palladacycle SpeciesBiomolecular Engineering
Novel [LPdCl]3 trimers (L = chiral secondary benzylamine) were synthesized via direct cyclopalladation. The structures of trimeric palladacycles were confirmed by means of X-ray analysis. The secondary interactions stabilizing trimeric molecules were investigated. An equilibrium between dimeric and trimeric palladacycle species was found in solution by means of dynamic NMR- spectroscopy and ESI mass spectrometry study.
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