Trimethylenemethane‐Ruthenium(II)‐Triphos Complexes as Highly Active Catalysts for Catalytic CO Bond Cleavage Reactions of Lignin Model Compounds

Abstract

R u ready for it yet? The reaction of [Ru(cod)(methallyl)2] with tripodal phosphine ligands of the TRIPHOS-type results in the formation of Ru-trimethylenemethane complexes. Evaluation of their catalytic properties revealed a high activity for hydrogen transfer and CO cleavage reactions including the hydrogen-free reductive cleavage of 2-aryloxy-1-arylethanols as model compounds for lignin linkages. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.