Ionic galleries: a bilayered host–guest cocrystal of C-propyl pyrogallol[4]arene with an ionic liquid

Abstract

We report on a cocrystal between C-propyl pyrogallol[4]arene and the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate exhibiting a remarkable bilayer topology comprising two unique host-guest complexes resulting from the ionic liquid cation binding in two distinctive orientations relative to the macrocycle.

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