Nitrogenase Model Complexes [Cp*Fe(μ-SR<sup>1</sup>)<sub>2</sub>(μ-η<sup>2</sup>-R<sup>2</sup>N═NH)FeCp*] (R<sup>1</sup> = Me, Et; R<sup>2</sup> = Me, Ph; Cp* = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>): Synthesis, Structure, and Catalytic N−N Bond Cleavage of Hydrazines on Diiron Centers - Concepedia

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Nitrogenase Model Complexes [Cp*Fe(μ-SR<sup>1</sup>)<sub>2</sub>(μ-η<sup>2</sup>-R<sup>2</sup>N═NH)FeCp*] (R<sup>1</sup> = Me, Et; R<sup>2</sup> = Me, Ph; Cp* = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>): Synthesis, Structure, and Catalytic N−N Bond Cleavage of Hydrazines on Diiron Centers

108

Citations

31

References

2008

Year

Yanhui Chen, Yuhan Zhou, Pingping Chen, Yinsong Tao, Yang Li, Jingping Qü

Journal of the American Chemical Society

Abstract

The reactions of [Cp*Fe(mu-SR1)3FeCp*] (Cp* = eta5-C5Me5; R1 = Et, Me) with 1.5 equiv R2NHNH2 (R2 = Ph, Me) give the mu-eta2-diazene diiron thiolate-bridged complexes [Cp*Fe(mu-SR1)2(mu-eta2-R2N NH)FeCp*], along with the formation of PhNH2 and NH3. These mu-eta2-diazene diiron thiolate-bridged complexes exhibit excellent catalytic N-N bond cleavage of hydrazines under ambient conditions.

References

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