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Photoinduced Allylation of Aromatic Carbonyl Compounds by Allylic Stannanes
22
Citations
3
References
1987
Year
Chemical EngineeringEngineeringPhotoredox ProcessPhotochemistryAbstract Irradiationγ-Unsaturated AlcoholsMechanistic PhotochemistrySynthetic PhotochemistryOrganic ChemistryChemistryAsymmetric CatalysisAromatic Carbonyl Compounds
Abstract Irradiation of aromatic carbonyl compounds and allyl-, 2-methyl-2-propenyl-, or 3-methyl-2-butenyltrimethylstannanes in acetonitrile afforded δ,γ-unsaturated alcohols as major product. A photoinduced electron transfer mechanism is proposed for the allylations.
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