Publication | Closed Access
Long-Lived Charge-Separated State Produced by Photoinduced Electron Transfer in a Zinc Imidazoporphyrin-C<sub>60</sub>Dyad
101
Citations
8
References
2003
Year
Organic Charge-transfer CompoundPhotoinduced Electron TransferChemical EngineeringCharge ExcitationsShort Linkage ResultsEngineeringPhotochemistryNatural SciencesMechanistic PhotochemistryLongest LifetimeExcitation Energy TransferPhysical ChemistryCharge SeparationQuantum ChemistryChemistryBiophysicsZinc Imidazoporphyrin-fullerene Dyad
[reaction: see text] Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 micros in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor-acceptor-linked dyads.
| Year | Citations | |
|---|---|---|
Page 1
Page 1