Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors

Bogdan Harbuzaru, Avelino Corma, Fernando Rey, Pedro Atienzar, J.L. Jordá, Hermenegildo Garcı́a, Duarte Ananias, Luís D. Carlos, João Rocha

Angewandte Chemie International Edition · 2008 · 401 citations · 29 references

Concepts

Abstract

Shining bright: Porous metal–organic framework materials are important owing to their potential applications as sensors. A new family of nanoporous, multifunctional rare-earth metal–organic materials displays emission quantum yields and efficiencies that are the highest reported for solid-state Eu3+ compounds with organic ligands and magnetic properties. The picture shows [Gd,Eu]- and [Tb]-containing materials under UV light and interacting with a magnet.

References

29