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A CONVENIENT METHOD FOR BROMOSULFENYLATION: REACTIONS OF SULFENAMIDES WITH OLEFINS IN THE PRESENCE OF POBr<sub>3</sub>
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Citations
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References
1999
Year
Medicinal ChemistryEngineeringSulfenylation ReactionHeterocyclicAlkene MetathesisNatural SciencesOrganic ChemistryCatalysisOne-pot TransformationChemistryHeterocycle ChemistrySynthetic ChemistryChemical DerivativePhosphorus OxibromideEnantioselective SynthesisBiomolecular Engineering
Abstract A general method for the one-pot transformation of alkenes into abromoalkyl-arylsulfdes has been proposed based on the sulfenylation reaction by means of sulfenamides in the presence of phosphorus oxibromide. The plausible reaction mechanism and the results of reactions with a number of model alkenes such as cyclohexene, I-heptene, norbornene and other from the bicyclo[2.2.1] heptane series are discussed.
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