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Ligand and Solvent Effects on Emission Lifetimes of Cr(III) Ammines.

DOIFull Paper Access

34

Citations

0

References

1979

Year

R.T. Walters, Arthur W. Adamson, Georg Johansson, Arne Holm, Nils H. Toubro, A. Krantz, J. Laureni
Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry

Abstract

Abstract : Emission lifetimes and their temperature dependence are reported for a number of CR(III) ammine complexes. A new set of rules governing emission from room temperature, fluid solution is proposed. A rationale for the rules is that thermal-type photosubstitution occurs from the First thexi doublet state and that the rate controls the lifetime. (Author)