The Journal of Chemical Physics · 1955 · 182 citations · 10 references
Natural SciencesChemistryMaterials ScienceMaterials ThermodynamicsPhysical ChemistryPolymer ChemistryDielectric MaterialsDielectric PropertiesDielectric ResponseDielectricsIntermolecular ForcesDielectric ConstantDielectric Constant MeasurementDielectric DispersionDielectric MeasurementDispersionsHydrogen BondingTemperature Dependence Of PermittivityTemperature-dependent Permittivity
Measurements of static dielectric constant were made for all except t-butyl alcohol from the boiling points to —140°C; dispersion and loss were measured below 0°C in the range 20 cy/sec to 2 Mc/sec. Multiple dispersions were found as in other alcohols. The temperature dependences of static values are examined in terms of finite extent of chainwise molecular coordination by hydrogen bonding, and the rate laws of the dispersions are discussed.
10
Electric Moments of Molecules in Liquids
Lars Onsager · Journal of the American Chemical Society · 1936 · 5.3K citations
The Dielectric Polarization of Polar Liquids
John G. Kirkwood · The Journal of Chemical Physics · 1939 · 1.9K citations
Natural Sciences, Chemistry, Physics +17